&GLOBAL
  PROJECT Cu
  PROGRAM_NAME ATOM
&END GLOBAL
&ATOM
  ELEMENT Cu
  ELECTRON_CONFIGURATION [Ar] 3d10 4s1
  &METHOD
     METHOD_TYPE  KOHN-SHAM
     RELATIVISTIC ZORA(MP)
     &XC
       &XC_FUNCTIONAL 
         &PBE
         &END PBE
       &END XC_FUNCTIONAL
     &END XC
  &END METHOD
&END ATOM
