#------------------------------------------------------------------------------
#$Date: 2010-01-30 15:59:17 +0200 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: svn://www.crystallography.net/cod/cif/2/2008199.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2008199
_journal_name_full 'Acta Crystallographica Section C'
_journal_year  1999
_journal_volume 55
_journal_page_first  293
_journal_page_last  296
_publ_section_title
;
Ag~2~[Pd(NH~3~)~2~(SO~3~)~2~] Powder
;
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
loop_
_publ_author_name
  'Solovyov, Leonid A.'
  'Blokhin, Alexander I.'
  'Mulagaleev, Ruslan F.'
  'Kirik, Sergei D.'
_chemical_name_common  'silver(I) diammino-disulfito-palladat(II)'
_chemical_formula_sum  'Ag2 H6 N2 O6 Pd S2'
_chemical_formula_structural  'Ag2 (Pd (N H3)2 (S O3)2)'
_chemical_formula_analytical  'Ag2.01 (Pd1.01 (N H3)1.95 (S O3)1.98)'
_chemical_formula_iupac  'Ag2 [Pd (N H3)2 (SO3)2]'
_chemical_formula_weight  516.33
_chemical_melting_point  'decomposes at 175\%C'
_symmetry_cell_setting  'monoclinic'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
  '-x, y+1/2, -z+1/2'
  'x, -y-1/2, z-1/2'
_cell_length_a  7.05180(10)
_cell_length_b  5.85100(10)
_cell_length_c  10.3799(2)
_cell_angle_alpha  90.00
_cell_angle_beta  108.2200(10)
_cell_angle_gamma  90.0
_cell_volume  406.80(3)
_cell_formula_units_Z  2
_cell_measurement_temperature  293
_diffrn_ambient_temperature  293
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
  Pd 0 0 0 1
  Ag 0.4396(2) -0.2340(3) 0.14780(10)
  1
  S 0.2515(6) 0.2626(8) 0.03580(10)
  1
  O1 0.4430(10)
  0.174(2) 0.1161(9) 1
  O2 0.2140(10)
  0.464(2) 0.1134(8) 1
  O3 0.2540(10)
  0.3550(10)
  -0.0960(10)
  1
  N -0.0960(10)
  0.1570(10)
  0.1485(9) 1
  H1 -0.150 0.294 0.119 1
  H2 0.010 0.176 0.223 1
  H3 -0.187 0.068 0.168 1
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Pd N . . 2.078(9) yes
  Pd S . . 2.288(5) yes
  Pd Ag . . 3.2960(10)
  yes
  Ag O1 . . 2.410(10)
  yes
  Ag O1 . 3_645 2.390(9) yes
  Ag O2 . 1_545 2.332(9) yes
  Ag O3 . 2_655 2.490(10)
  yes
  S O1 . . 1.450(10)
  yes
  S O2 . . 1.500(10)
  yes
  S O3 . . 1.480(10)
  yes
  N O3 . 2_565 3.050(10)
  yes
  N O3 . 4_566 3.000(10)
  yes
_cod_database_code 2008199
